Method of producing phenylisothiocyanate
专利摘要:
A compound of the formula: <IMAGE> wherein X is oxygen or sulfur; R1 is hydroxy, C1-C4 alkoxy, phenoxy, amino, C1-C4 alkylamino, C2-C8 dialkylamino, C6-C10 arylamino, tetrahydrofurfurylamino, morpholino or methylpiperazino, but when X is sulfur R1 must be amino, C1-C4 alkylamino, C2-C8 dialkylamino or morpholino; R2 is C1-C4 alkoxy or C2-C5 alkoxycarbonyl; R3 is hydrogen C1-C4 alkyl, C1-C4 alkoxy, C2-C8 dialkylamino or halogen and its salts being useful as agricultural fungicides are provided. 公开号:SU1022657A3 申请号:SU782672305 申请日:1978-10-04 公开日:1983-06-07 发明作者:Огата Масару;Ватанабе Есихати;Мацумото Хироси;Тамара Кацуя 申请人:Сионоги Энд Ко., Лтд (Фирма); IPC主号:
专利说明:
Me x-xx-x-b 55.68 / 55.66 4.67 / ", 63 5.90 (lH5. OMe 53.80 / 53.96 4.06 / 4.09 6.27 CH-xCHOOOMe 52 , $ 17 (IR y iOOMe 52.35 .OjNS, 0, NS C, H ,, / 5.89 13.51 / 13.55 -80.3 14.36 / 14.26 - 59.2 / 6, 25 - 78.3 ohm (iH s; 100Me "iOOEV, OE JOI SCK СООМб - $ CH - -SX COOCH 55,12 / 55,22 Me 59,07 / 59,27 OMe. 57,59 / 57,46 5.64 / 5.63 11.20 / 11.04 Me Me 54.13 / 54.08 5.30 / 5.21 10.52 / 10.54 OMe56.82 / 56.92 5.64 / 5, 62 11.04 / 11.30: OMe 54.13 / 54.04 5.30 / 5.38 10.52 / 10.22 Table continuation - 84.3 - 64.3, 0, N, S "1/10 H, 0. 55.68 / 56.16 4.67 / 4.78 5.90 / 5.87 13.51 / 13.55 - 58.7 52.17 / 52.28 4.38 / 4.40 5.53 / 5.48 12.66 / 11.98 57, 35 / 57.27 5.21 / 5.23 5.58 / 5.62 12.76 / 12.55 - 67.6 57.37 / 57.27 5 , 22 / 5.21 5.58 / 5.49 12.76 / 12.77 C, C, H., o, NS C, NS 1 H 7 6.00 / 5.854.95 / 4.14 11 , 31 / 12.70 .S 6.10 / 6.10 10.60 / 10.48 12.13 / 12.31 12.81 / 12.78 - 75.9 12.04 / 12.10 - 57, 2 12.64 / 12.76 - 91.1 12.04 / 12.03 -42.8 Elemental analysis JR analysis Compound. .. Continued. TaOlitz / “- - 4 (calculated / found} j% (calculated / found / 7“ dctg - t1 - rg, d- i..Ji ... .. (iooMe .x., OMe AY 25K) ... JK3i El $ (51.24 / 50.77 3.94 / 3.98 4.98 / 4.73 11.40 / 11.94 -57.0 59.07 / 59.27 6.10 / 6.10 10.60 / 10.48 12.13 / 12.31 -64.3 C, NS, N, S 26 27 30 31 33 Continuation of the table Me 4x; 2s.OM € TOT / bit i (iH, 79 / 59.82 7.21 / 7.20 13.08 / 12.97 9.98 / 10.12 -64.7 MSH with H. S, -. We TOT j54,13 / 54,065,30 / 5,3010,52 / 10,5212.04 / 11,88- 51,4 IfiU С OOMe 11,5 O N2SCI (iONH-Yu 58,87 / 58,91 4.36 / 4.28 8.08 / 8.02 9.24 / 9D4 10.22 / 46.0 (ilv OMe iOOM "46.61 / 46.753.13 / 3.06 5.44 / 5 ,. i -lVSY bC HnOiNzSCl / 13.62 1C J. 48.80 /, 8.69, 9910.35 / 10.3411.84 / 11.9513 / 58.1 We / 13.29 Hl.WfiC ,, N4SCl 1GI., Lj ":: ttSWHC 46.79 / 46.773.53 / 3.43 10.91 / 10.9112.49 / 12.5913.81 / 56.2 16G p ull OSHLLO - 51,, 46 / 51.42 4.63 / 4.68 8.57 / 8.62 10.65 / 10.83-9.81 / 5, Me it "y oow 53.80 / 53.924.06 / 4.11 6.27 / 6.3514.36 / 14.06 - 6.0 C gligO NSCl, 46 12.44 / 12.58 13.76 / 41.0 / 13, so. (: 1CP5, C15 / 10.12 Sed i ХХ Me ffiT (iN 0 37 tS. 38 O6uiHft output from the corresponding 55.68 / 55.83 5.75 / 5.78 9.99 / 9.9022.87 / 22.60 - 58.8 54.52 / 54.645.23 / 5.18 9.08 / 9.1020.79 / 20.88- 59.9 49.25 / 49.54 4.51 / 4.56 10.45 / 10.3423.91 / 24, 16, - 64.8 twinkie nitrocompound. Same as in example 34 ,, ON, S2 Sichb 2 2 2 I. 9102265710 Phenylisothiocyanates of the formula (I) NTO-mealy dew is pumpkin, false is to be used as dew is pumpkin, anthracnose agricultural fungicides vtykvenny, pests of rice. vygo rasborebVe with various fiuopathogennymi and diseases, caused by digesters, in particular with such, various plant cultures.
权利要求:
Claims (1) [1] (541 METHOD FOR PRODUCING Phenylisothio cyanate of the general formula where C4-Cg-alkoxy, hydroxyl, amino, methylamino, C ^ -C ^ dialkylamino, phenoxy, methyl piperazino, morpholino, tetrahydrofurfurylamino, dimethylanilamino, diethylaminoethyl; R 2 - C4-C alkoxy, ethoxycarbonyl / Rj is hydrogen, methyl, methoxy, chlorine, dimethylamino, and the fact that the compound of the general formula where R <- Rj have the indicated meanings, is reacted with carbon disulfide in an organic solvent in the presence of triethylamine with subsequent processing of the resulting reaction product with alkyl halocarbonate.
类似技术:
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同族专利:
公开号 | 公开日 NO783323L|1979-04-05| IL55675D0|1978-12-17| GB2005268A|1979-04-19| IE47663B1|1984-05-16| CH637636A5|1983-08-15| FR2405244B1|1981-12-11| AU518311B2|1981-09-24| IE781962L|1979-04-04| US4248869A|1981-02-03| ES473896A1|1979-10-16| CA1091669A|1980-12-16| NL7810026A|1979-04-06| BR7806553A|1979-05-02| SE7810312L|1979-04-05| FR2405244A1|1979-05-04| IT7869295D0|1978-10-04| JPS5455550A|1979-05-02| IL55675A|1982-11-30| DE2843291A1|1979-04-12| BE870991A|1979-02-01| GB2005268B|1982-06-23| JPS6034542B2|1985-08-09| NO146059C|1982-07-21| NO146059B|1982-04-13| US4228165A|1980-10-14| AU4037678A|1980-04-17| DK435978A|1979-04-05| IT1108121B|1985-12-02|
引用文献:
公开号 | 申请日 | 公开日 | 申请人 | 专利标题 RU2490256C2|2008-02-29|2013-08-20|Ниссан Кемикал Индастриз, Лтд.|Method of producing isothiocyanate compound containing carboxyl group|NL290565A|1962-03-23| US3781360A|1966-01-14|1973-12-25|Schering Corp|2-polyfluoroloweralkylamino benzophenones| US3755358A|1966-01-14|1973-08-28|Schering Corp|2--n-)aminobenzophenones| US3449112A|1966-02-04|1969-06-10|Upjohn Co|P-isothiocyanatobenzoates as herbicides| US3480424A|1966-02-04|1969-11-25|Upjohn Co|Phenylisothiocyanates as herbicides| DE1793480A1|1968-09-24|1972-02-24|Basf Ag|fungicide| DE2013788A1|1970-03-23|1971-10-21|Farbenfabriken Bayer Ag, 5090 Lever Kusen|Aryl isothiocyanate miticides| GB1318681A|1971-01-01|1973-05-31|Shell Int Research|Phenyl ketoxime derivatives|FR2485526B1|1980-06-24|1983-11-25|Shionogi & Co| US4680338A|1985-10-17|1987-07-14|Immunomedics, Inc.|Bifunctional linker| JPH0752055Y2|1989-06-14|1995-11-29|株式会社ミドリ十字|Antibacterial container| US5436268A|1989-11-09|1995-07-25|The Green Cross Corporation|Processes including germ-destroying step, germicidal products and their preparation method, fumigant and fumigation method, as well as germicidal gas compositions, their preparation method and apparatus therefor| AU6635990A|1989-11-09|1991-06-13|Minato Company Ltd.|Process involving sterilization step, product having bacteriocidal activity and process for preparing the same, fumigant, fumigation method, and bacteriocidal gas composition, and process and apparatus for preparing the same| PL170837B1|1991-10-18|1997-01-31|Monsanto Co|Fungicide| GEP20002224B|1992-10-02|2000-06-10|Monsanto Co|Fungicides for the Control of Take-All Disease of Plants| CA2124137A1|1993-05-25|1994-11-26|Mitsuhiro Matsumoto|Process for producing aromatic isothiocyanate derivatives| US5482974A|1994-03-08|1996-01-09|Monsanto Company|Selected fungicides for the control of take-all disease of plants| US5486621A|1994-12-15|1996-01-23|Monsanto Company|Fungicides for the control of take-all disease of plants| ES2211577T3|1999-08-13|2004-07-16|Monsanto Technology Llc|AMIDAS OXIMA AND AMIDAS HIDRAZONA WITH FUNGICIDE ACTIVITY.| EP2647623A4|2010-11-29|2015-12-30|Nissan Chemical Ind Ltd|Method for producing isothiocyanate compound|
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申请号 | 申请日 | 专利标题 JP52119789A|JPS6034542B2|1977-10-04|1977-10-04| 相关专利
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